It shows that calculation methods can be useless for the preliminary lipophilicity determination of such a kind of compounds. The reason can be the specific special structure of the tested phenothiazine derivatives consisting of tetracyclic system with additional nitrogen atom. No computer programs gave values of log P calc close to values of log P TLC obtained experimentally. The thousands separator should be commas, when the decimal point is a full stop. The results of log P calc for the compounds 1–13 were quite different according to the computer program used (log P calc = 1.69–5.98). There is a hint in the placeholder on how to install lua (brew install lua53) Sure, good point. Also, none of the computer programs gave values of lipophilicity parameters close to these obtained by experimental method. None of the computer programs took into consideration the influence of substituents in a structure of the tested compounds, and in this case, the calculated lipophilicity parameter had the same value for all isomers with the same substituent. The computer programs applied based on different theoretical approaches gave different values of lipophilicity parameters depending on the kind of substituent in the quinobenzothiazine system. 124 in Utilities 4.7 546 Ratings 9. Phenothiazine derivatives were modified mainly by introduction of substituents into the nitrogen atom of the thiazine ring. Also, cluster analysis was performed for the data obtained. The correlation between the experimental and the theoretical values of lipophilicity was found. Experimental lipophilicity parameters ( R M0 and log P TLC) were determined by use of thin-layer chromatography, and also some theoretical values of lipophilicity were calculated by use of computer programs. These are newly synthesized compounds, which were previously analyzed taking into consideration biological activity and their antiproliferative activity. The aim of this work was the application of thin-layer chromatography to the lipophilicity analysis of selected quinobenzothiazine derivatives.
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I am solely responsible for any false disclosures or legal ramifications of viewing, reading or downloading any material appearing on this site.The viewing, reading and downloading of sexually explicit materials does not violate the standards of any community, town, city, state or country where I will be viewing, reading and/or downloading the Sexually Explicit Materials.I believe that sexual acts between consenting adults are neither offensive nor obscene.I believe that as an adult it is my inalienable constitutional right to receive/view sexually explicit material.I desire to receive/view sexually explicit material.The sexually explicit material I am viewing is for my own personal use and I will not expose any minors to the material.I have attained the Age of Majority in my jurisdiction.§ 1746 and other applicable statutes and laws that all of the following statements are true and correct: Do NOT continue if: (i) you are not at least 18 years of age or the age of majority in each and every jurisdiction in which you will or may view the Sexually Explicit Material, whichever is higher (the "Age of Majority"), (ii) such material offends you, or (iii) viewing the Sexually Explicit Material is not legal in each and every community where you choose to view it.īy choosing to enter this website you are affirming under oath and penalties of perjury pursuant to Title 28 U.S.C. DnD Dice Roller can help when the dice rolls get too large or to save time during preparation and gameplay.This website contains information, links, images and videos of sexually explicit material (collectively, the "Sexually Explicit Material"). But sometimes there are roll requirements that become difficult and time-consuming when performed with physical dice. Part of the fun of playing is having a personal collection of dice. There can be many different dice types, numbers and combations required to play a game. Most players roll 2d10 instead, where two dice become the 1's and 10's places, with two 10's (often represented as '00') being 100. Not really a die, the 'Zocchihedron' is a ball with a hundred flattened faces. Made up of twenty triangular-shaped faces. If you thought the d12 looked ball-like, this one is a step closer. Twelve pentagonal faces combine to form this multi-sided die.Īn icosahedron, or twenty-sided shape. This die is starting to look less like a die and more like a ball. Similar in appearance to the d8, but in this case two pentagonal pyramids with bases pressed together.Ī dodecahedron. Looks like two four-sided pyramids pressed together at the base.Ī decahedron. Used by most tabletop games.Īn octahedron. The simplest three-dimensional shape that can be accomplished for dice-rolling purposes.Ĭlassic and most typical type of die. Some tabletop games require a d3 roll, but this is usually accomplished by rolling a d6 and halving the result.Ī tetrahedron, or a 3-sided pyramid shape. So for example, a D&D player who was rolling a strength score for a new character would need to roll 3d6, or three(3) 6-sided dice.ĭnD Dice Roller allows all types of dice rolls required by D&D and most other tabletop games, as per the table below.Īny two-faced object could be used but typically a coin toss is sufficient when a d2 is required.Ī theoretical die only. Furthermore, where a number of dice are required it is notated as 'Xd', where 'X' is the number of dice to roll. A 6-sided die would be referred to as d6 or a 10-sided die as d10. While most tabletop games use standard 6-sided dice, there are some games which require a range of specially-sided dice, such as 4-sided, 8-sided or even 100-sided dice!Ī standard form for abbreviating these different types of dice is by using the notation 'dX' where 'd' refers to a die(singular) or dice(plural), and 'X' represents the number of sides. For questions, comments, to report a bug or request a feature, please contact the Site Administrator by completing this contact form. If this is your first time using the site, be sure you've read the how to use section for basic instructions on creating and customizing your own dice combinations. DnD Dice Roller is an online virtual dice roller for Dungeons & Dragons or any tabletop game where dice are required. It gets every good that it earns, and it suffers every ill that it earns. 2.Whatdo the Qur'an and Sunnah say about this Allah says in Surah Baqara 2:286 "On no soul doth Allah place a burden greater than it can bear. A person does an act of Sawaab (reward) and intends that the reward of that act gets transferred to someone else, normally a person who is dead. 1.Eesaale Sawaab meaning "Eesaal e Sawaab" means trnsferring Sawaab. Is it possible to do "Eesaal e Sawaab" to those who are dead, hence transfer Sawab to those who are dead? Answer. The Quran says: “We shall unite the true believers with those of their descendants who follow them in their faith, and shall not deny them the reward of their good deeds – everyone is responsible for his deeds. The best thing those of his relatives who have been left behind can do for him is to do good deeds themselves so that they too can join him in the Paradise in the hereafter. If he was a pious and God-fearing person then he will insha’Allah go to the paradise. If God Almighty would will, He will accept your prayer keeping in view the performance of the deceased. All that you can do for the benefit of the deceased is to pray for him as much as you can. It is now the trial of those who have been left behind. There is no point in doing any act of piety on his behalf now that his trial is over. The Quran says: “… no soul shall bear the burden of another, … there shall be nothing for a man except what he strives for” (53:38-39) Nobody can add anything to the credit of an individual’s account. If anyone introduces an innovation or gives shelter to a man who introduces an innovation (in religion), he is cursed by Allah, by His angels, and by all the people.” Avoid novelties, for every novelty is an innovation, and every innovation is an error.” (Abu Daud) The same book reports another statement attributed to him thus: “If anyone introduces an innovation, he will be responsible for it. The prophet, alaihissalaam, said: “You must follow my sunnah and that of the rightly-guided caliphs. Occasions like Qul, Chaliswan, and Barsi are not only useless, they are very likely to be categorized as bid’at which is an attempt to add to (innovate) God’s religion something that was not given by His messenger, alaihissalaam. In fact, nothing has been recommended to be recited after the death of an individual except that we should say Janaza prayer for him or pray for his forgiveness after burying him or even later whenever we feel like. However, it has not been recommended after the death of an individual. There is a mention in the hadith literature that if a person is dying we should recite surah Ya-Sin over him. Can one give food or money to the poor in the name of the deceased? Or is it that only the charity given out in a person’s lifetime is counted? There was also a concern from my Nani’s side regarding “Qurbani” on “Eid ul Adha”, she wanted to sacrifice two goats one for herself and the other in her deceased husband’s name and she was torn between doing the Qurbani or sending equivalent amount of money to the victims of Tsunami. In the end I would like you to comment on all the ways (if any) a family can send Sawab to the deceased. Please guide me regarding this issue and if possible please site any relevant ayas or ahadith. And secondly what all can the immediate family members do to provide “Sawab” to the deceased’s soul? As far as i know, I don’t think there is any requirement for Quls, Jumairats and Chaliswans as it only adds to the sorrow instead of reducing it without helping the deceased in any way. I dont know if the recitation of the Quran really helps the deceased in any way. My Nani also held the “Jumairats” and then the “Chaliswan” when again the entire Quran was recited. Then my Nani placed white sheets in the drawing room till my Nana’s “Chaliswan” and we were all asked to recite the Holy Quran and Surah Yasin but for some reason I wasn’t very comfortable with that because not only was the environment very depressing (it maintained the sorrowful ambiance) I was under the impression that only 3 days sorrow is allowed and after that people should get on with their daily routines. We also held ‘Quls’ the next day for which we recited “Surah Ikhlaas”. First we were not sure of what to recite when he was on his death bed so we all started by reciting Surah Yasin until he passed away then we all recited “Kalima Tauhid” till his “Janaza”, however my Nani insisted on reciting Surah Yasin even after that. My Nana passed away in September and none of us had the knowledge of what is required of the family members of the deceased in the light of Islam. After a 1–1 draw with Championship team Reading at the Madejski Stadium in the Third Round, Liverpool lost the replay at Anfield 2–1 after extra time. They were then knocked out of the FA Cup on 13 January. They were eliminated from the League Cup at the hands of Arsenal in the Fourth Round in a 2–1 defeat at the Emirates Stadium on 26 October. This season Liverpool made major moves in the transfer market, selling important players such as Xabi Alonso and Sami Hyypiä, while signing Alberto Aquilani from Roma and Glen Johnson from Portsmouth.Īfter a season of poor results and inconsistent play, as well as injuries to main striker Fernando Torres, Liverpool finished 7th in the Premier League, their lowest finish in 11 years, and failed to progress beyond round 4 of either domestic cup. Having finished second in the previous league campaign, Liverpool qualified automatically for the 2009–10 UEFA Champions League group stage for the first time since the 2002–03 season. His association with the club would also end at the end of the year, however. Rafael Benítez was the club's manager, this being his sixth season in charge. They were sponsored for an eighteenth season by Carlsberg, but this association would end at the end of the year. The 2009–10 Premier League was Liverpool's 118th season since their foundation, and their 48th consecutive year in the top flight. 45 Environmental Initiative, Environmental Studies & Environmental Policy. 133 Advanced Technology For Large Structural Systems (ATLSS) Research Center. 23 Curricular Flexibility - Transfer Between Colleges. 22 International Center for Academic and Professional English. 20 Lehigh University Art Galleries – Museum Operation (LUAG). 19 Guidelines for Undergraduates to Take Graduate Level Courses. 17 Special Undergraduate Academic Opportunities. Be sure to provide specific examples of practices and/or values in your discussion. 32 In Bethlehem, An Educational Tradition. In a 1,250-1,500-word essay, identify similarities and differences between servant leadershipâs philosophies and the values evident in the selected cultural context and religious viewpoint. 30 Information for All Financial Aid Applicants. 27 Estimate of Expense for Undergraduates. 10 Guide to Academic Rules and Regulations. 10 Five-Year, Two-Bachelor-Degree Programs. 5 Lehigh University/United Nations Partnership. 4 International Students and Scholars Office. Please refer to the directions in the Student Success Center.Published since 1866 continuously, Lehigh University course catalogs contain academic announcements, course descriptions, register of names of the instructors and administrators information on buildings and grounds, and Lehigh history. You are required to submit this assignment to Turnitin. Refer to the rubric attached titled, “Topic 3: Servant Leadership in Diverse Contexts,” prior to beginning the assignment to become familiar with the expectations for successful completion. Prepare this assignment according to the guidelines found in the APA Style Guide, located in the Student Success Center. Servant leadership has often been seen as. They include humility, ethics, integrity, courage, authenticity, forgiveness, and hope (Roberts, 2018). To be a servant leader, leaders have to possess certain virtues. A practitioner is a witch.In medieval and early modern Europe, where the term originated, accused witches were usually women who were believed to have attacked their own community, and often to have communed with evil beings. Include information from the articles in your discussion. The servant-leader understands the motivation and potential of their followers and builds on this to achieve a common and shared goal. Witchcraft traditionally means the use of magic or supernatural powers to harm others. Be sure to select academic articles from reputable sources that are 10-20 pages in length. You are required to locate two articles that examine servant leadership from a different cultural perspective and two articles that examine servant leadership from a different religious perspective. In a 1,250-1,500-word essay, identify similarities and differences between servant leadership’s philosophies and the values evident in the selected cultural context and religious viewpoint. Select one cultural context and one religious viewpoint (other than Christianity, its denominations, or something already discussed in the textbook) and examine how the principles of servant leadership are evident in that culture and religion. This assignment presents you with an opportunity to explore other cultures, philosophies, and religions and asks you to think critically about how servant leadership practices are apparent in other religious and cultural values. While servant leadership is often associated with Christianity and the Bible, one could argue it is compatible with most religions and philosophies and that it transcends cultures. These styles are suitable for book vintage logo style, flyer, banner, poster, retro style, Book cover, game text your next project. So enhance your artwork with these styles and give it a vintage look. You can apply these styles to your text/artwork with just one click. This is a pack of 10 different retro text effects for Adobe Photoshop. With high quality and premium effects can produce the effect of a more perfect and interesting to all your texts and all style effects work only with one click. 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What keeps Otto Matic fresh is the variety of enemies and how the player must use different weapons and power-ups to most effectively deal with them. You'll explore the various locales looking for humans to rescue and enemies to fight or avoid. Gameplay in Otto Matic follows the tried and true formula found in most games of the genre. The metallic quality of his body is well represented by the sounds it makes interacting with the environment around him. Sound effects are competently executed, particularly Otto's. Depending on how well you're playing, it could do both. It has a very retro feel that will either further engross you in the experience or will just begin to annoy you. The music in Otto Matic is in line with the theme of a campy sci-fi movie. Gamers looking to push their graphics cards to their limits might be put off by the somewhat simplistic graphics, but the presentation is full of character and allows the game to run at a solid framerate on even modest hardware. The world is lush and colorful with a cheerful, Nintendo-like quality that doesn't take itself too seriously. In an era of games striving for realism in their graphics, Otto Matic comes as a welcome respite. The graphical style of Otto Matic is clearly reminiscent of previous Pangea titles, and that's not a bad thing. Because the aliens have taken the humans to far-ranging planets, you too must travel the galaxy to rescue them. In the game you take on the role of Otto Matic, a friendly robot, who must save humanity from the evil Brain Aliens of Planet X. The dashboard aboard the Terra especially stands out with its silver accents surrounding the touchscreen and the aircon controls. Of course, if you’re intending to take a Nissan Terra off-road on the regular, we highly suggest getting the top of the line Nissan Terra 2.5 4x4 BL AT.ĭespite being based on the Navara pick-up truck, the Nissan Terra stands apart from the former by having a distinct interior and exterior. As such, it has a body on frame construction thus making it capable of dealing with harsh terrain right out of the dealership. Specifically, the D23 Nissan Navara pick-up truck. The Nissan Terra like most of its currently available mid-size competitors is based on a pick-up truck. The Nissan Terra shares a lot of characteristics with the Navara but it does have a much more significant road presence That’s on top of being released more recently that most of its current competitors the Toyota Fortuner, the Isuzu Mu-X, and the Mitsubishi Montero Sport. While the Nissan Terra isn’t the largest SUV in Nissan PH’s lineup, it is one of the more popular mid-size SUVs in the country right now to the point that it is one of the company’s best sellers. 1.Terra: A popular mid-size Nissan SUV Philippines The Nissan Terra mid-size SUV, and the Nissan X-Trail compact crossover SUV. In recent times, Nissan Philippines currently has three SUVs in its line-up the Nissan Patrol Royale, the largest of the bunch. has reviewed the content to ensure it is relevant.We have listed the SUV model lineup from major brands before, but for this article, we’ll be focusing on SUVs from Nissan.Įver since their first sport utility vehicle, the mid-sized Nissan Pathfinder, the company has produced excellent vehicles that have captured the attention of the Filipino SUV buyer. In some cases, will work with advertisers to bring you relevant content that has been made possible by advertisers and their partners. Opinions expressed within editorial material are those of the writer and not necessarily Ltd.įor further information, see our Terms & Conditions. If the price does not contain the notation that it is "Drive Away No More to Pay", the price may not include additional costs, such as stamp duty and other government charges. When purchasing a vehicle, always confirm the single figure price with the seller. Pricing guide current at the time of writing editorial. In most cases, attends new vehicle launches and other events at the invitation and expense of vehicle manufacturers, importers and/or distributors.Įditorial prices shown are a "price guide" only, based on information provided to us by the manufacturer. Here’s what’s coming from Nissan next year. However, many of Nissan’s new-for-2022 models have been pushed back to later next year due to supply issues and the Japanese brand remain cagey on exact arrival times. “From the return of our iconic Z to the rugged yet refined Pathfinder, the stylish QASHQAI to the adventure-ready X-TRAIL, I can confidently say there is an all-new vehicle for everyone in 2022.”įollowing this month’s release of the swansong GT-R T-Spec limited-edition, after which the current Godzilla will be discontinued Down Under, and next month’s launch of the upgraded Navara Warrior ute, the replacement of Nissan’s small, medium and large SUVs, plus the first Patrol Warrior and new Z coupe, will see the update or renewal of Nissan Australia’s entire model range. “Next year will be a huge 12 months for Nissan, as we undertake an almost brand-wide refresh with the launch of four incredibly exciting and all-new models,” said Nissan Australia managing director, Adam Paterson. Nissan Australia is gearing up for what it claims will be the biggest year in its history, with no fewer than three all-new SUVs, the redesigned Nissan Z sports car and the Toyota LandCruiser-thrashing Patrol Warrior all on the starting blocks for release in 2022. You must keep the control key during the installation and then your device unlocks the fully signed program. Soundflower Mac | Installation and Use:Īlthough macOS Soundflower comes in a very small package (less than 100 kb), installing it takes a little more than standard Mac Apps since the installer is not signed. If a software does not permit you to specify audio devices, you could make Soundflower the default enter or output device in the Sound panel inside the System Preferences, or with the Audio MIDI Setup utility software that’s the best barely difficult part. If you need an application to have interaction with some other software through the soundcard, select Soundflower as the output tool within the first software and Soundflower because of the input tool in the 2d software. For most human beings and needs, the 2-channel tool is sufficient. It opens as considered one of the audio devices (2ch/16ch). Soundflower Mac emulates the interface of an audio device but lets in any audio software to ship and obtain audio without the other aid needed. Have you ever wanted to enable the software to get the right of entry to your soundcard or engage with another application via the soundcard? Soundflower Mac is a free audio gadget extension that permits packages to skip audio to other programs. Allow different programs to get right of entry to your soundcard: ✅ Soundflower Mac Free Downloadtrendy version: 2.0 Beta 2. 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His bandmates were happily walking around the stage singing their lines of the song that was loudly heard from the speakers, a huge screen was broadcasting in real time everything they were doing. The stadium where they were strolling, jumping and dancing to their songs was huge, holding at least thousands of people who had come only and solely to see the band on stage. TaeHyung had always loved that feeling that ran through his body until it settled in his chest, that feeling of being loved by hundreds and hundreds of people who admired his talent. The fans screaming, clapping and even dancing with them, singing and cheering filled his chest with a pleasant warm feeling. The euphoric shouts of the crowd surrounding the huge stage could be heard even in the innermost corner the thunderous crowd pierced even the special headphones they used to wear, making him smile knowing that they were shouting his name with such excitement. In the front row two meters away from the stage was that boy who managed to sneak into his head for a long, long time. He remembered him there in the crowd, his orange hair stood out among the blanket of brown and dark heads, his screams could be overshadowed by the fuss of the people but he managed to hear him as he passed by his row. He remembered him perfectly he remembered him as if it had been three days since that concert when he saw him for the first time and not six months as it really was. |
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